This page on SARS payment rules should help.
In brief - search for SARS as a listed company beneficiary - this should produce a list that looks like this:
Add the relevant beneficiary to your list of beneficiaries.
When it comes to the payment reference number (or PRN) the structure has three parts:
First 10 digits - taxpayer registration number
11th character - tax type indicator (V in the case of VAT)
last 8 digits - the period in the format 00mmyyyy
So assuming a VAT registration number of 1234567890 as example, the reference for a payment for the August 2013 period would be as follows:
1234567890V00082013
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